.Net邮件发送，报错mail from address must be same as authorization

代码：

SmtpClient smtpClient = new SmtpClient();

smtpClient.EnableSsl = true;

smtpClient.UseDefaultCredentials = false;

smtpClient.Host = "smtp.esmail.qq.com";

smtpClient.Port = "25";

smtpClient.Credentials = new System.Net.NetWorkCredential(发送邮件的邮箱，安全码);

smtpClient.Send(msg);

报错：

mail from address must be same as authorization

原因：

发送邮件在设置里开启服务：